Dr. No (1962)

Bob Simmons
James Bond in Gunbarrel Sequence (Uncredited)
Most people do not know that the first James Bond to appear (in an official movie of course) is not even Sean Connery. Bob Simmons’ likeness was used instead to make the famous walk-turn-shoot routine.
From Russia with Love (1963)

Bob Simmons
James Bond in Gunbarrel Sequence (Uncredited)
Once again, Simmons takes on his ‘role’ of James Bond in the opening gunbarrel sequence.

Anthony Dawson
Ernst Stavro Blofeld (Uncredited)
More known for his role as the creepy henchmen Professor Dent in Dr. No, Dawson appears as head of SPECTRE Blofeld in this movie, although, as the tradition is with Blofeld, only Dawson’s lower half is visible.

Eric Pohlmann
Ernst Stavro Blofeld (Voice – Uncredited)
This Austrian actor voiced the head of SPECTRE in the second James Bond movie.

Ian Fleming
Man Standing Next to Train (Uncredited)
Bond’s creator can be seen after Bond and Tatiana Romanova get on the Orient Express, after the train passes the man in the car, and seems to have a cow or some animal nearby.
Goldfinger (1964)

Alf Joint
Capungo, the Assassin
Longtime famed stunt coordinator Alf Joint takes on Bond in an exciting pre-title sequence. Joint’s character is eliminated by electrocution, prompting Bond to utter the famous line, “Shocking. Positively shocking.”

Bob Simmons
James Bond in Gunbarrel Sequence (Uncredited)
Bob Simmons comes back for a third time as 007 in the opening gunbarrel sequence.

Michael G. Wilson
Soldier (Uncredited)
In his first of many on-sreen cameos, the famed James Bond producer makes an appearance as one of Goldfinger’s soldiers at Fort Knox. This screenshot is of my own determining. Since most of Goldfinger’s soldiers were of Asian decent, and are relatively short in height, Wilson appears to stick out like a sore thumb in this shot. I could be wrong though, so e-mail me if you have any info.

George Leech
Man in Bulletproof Vest at Q Branch (uncredited)
This English actor and stuntman eventually makes multiple roles throughout the James Bond series, the first of which comes in this memorable scene from Q Branch in Goldfinger.
Thunderball (1965)

Anthony Dawson
Ernst Stavro Blofeld (Uncredited)
Dawson makes his third appearance in a Bond movie, and second as Ernst Stavro Blofeld in Thunderball.

Kevin McClory
Smoking Man (Uncredited)
This producer and longtime Bond movie Crew alum appears as a man sitting and smoking a cigar as Bond enters the Nassau Casino. McClory’s connection with the Bond franchise has been rough at times. Later in his Bond career, McClory claimed the rights to the Blofeld/SPECTRE organization in the early Bond movies. This prevented SPECTRE from being included in 1977’s The Spy Who Loved Me. In 1983, McClory produced the unofficial James Bond movie Never Say Never Again, starring Sean Connery as James Bond.

Charles Russhon
Air Force Officer (Uncredited)
Charles Russhon contributed to the Bond movies as a military advisor. He is shown in the above image sitting on M’s desk. Russhon was acknowledged in Goldfinger a year earlier, as his name appeared on Fort Knox’s sign.

Bob Simmons
Colonel Jacques Bouar (Uncredited)
Bob Simmons takes on Sean Connery in a fight sequence at the beginning of this movie. This was a departure from Mr. Simmons’ normal Bond ‘role,’ that of playing the opening gunbarrel Bond.

George Leech
Disco Volante Crewman (uncredited)
The longtime actor and stuntman that cameos in the Bond movies appears as a member of Largo’s crew on the Disco Volante (he is on the left in the above screenshot from the movie).
On Her Majesty’s Secret Service (1969)

Peter R. Hunt
Man in Reflection of Universal Exports sign (Uncredited)
The movie’s director Peter Hunt shows his face in the blurry sign of James Bond’s cover-up company at the beginning of this film.

George Leech
Strangled SPECTRE Skier (Uncredited)
The stuntman appears as one of the SPECTRE goons chasing Bond down the slopes of the Swiss Alps, and is eventually strangled with Bond’s ski.